Search results for "Correction method"

Application of point-to-point matching algorithms for background correction in on-line liquid chromatography–Fourier transform infrared spectrometry …

2009

A new background correction method for the on-line coupling of gradient liquid chromatography and Fourier transform infrared spectrometry has been developed. It is based on the use of a point-to-point matching algorithm that compares the absorption spectra of the sample data set with those of a previously recorded reference data set in order to select an appropriate reference spectrum. The spectral range used for the point-to-point comparison is selected with minimal user-interaction, thus facilitating considerably the application of the whole method. The background correction method has been successfully tested on a chromatographic separation of four nitrophenols running acetonitrile (0.08…

Dangerous relationships : biases in freshwater bioassessment based on observed to expected ratios

2018

Copyright by the Ecological Society of America The ecological assessment of freshwaters is currently primarily based on biological communities and the reference condition approach (RCA). In the RCA, the communities in streams and lakes disturbed by humans are compared with communities in reference conditions with no or minimal anthropogenic influence. The currently favored rationale is using selected community metrics for which the expected values (E) for each site are typically estimated from environmental variables using a predictive model based on the reference data. The proportional differences between the observed values (O) and E are then derived, and the decision rules for status ass…

Determination of critical eluent composition for polyethylenglycols using on-line liquid chromatography-Fourier transform infrared spectrometry.

2008

In this work, it has been extended to methanol:water mobile phases, the use of a background correction method for on-line LC-FTIR measurements named Univariate background correction based on the use of a reference spectra matrix (UBC-RSM) and absorbance ratios. It permits to overcome the problem related to spectral changes occurring during the gradient elution, which in the past limited the on-line coupling of LC and FTIR to isocratic elutions. The combined use of the aforementioned background correction technique in on-line isocratic and gradient LC-FTIR, and partial least squares (PLS) has been applied for the search of the critical conditions for polymers. Polyethylenglycol (PEG) has bee…

Mode-superposition correction method for deterministic and stochastic analysis of structural systems

2001

The role played by the modal analysis in the framework of structural dynamics is fundamental from both deterministic and stochastic point of view. However the accuracy obtained by means of the classical modal analysis is not always satisfactory. Therefore it is clear the importance of methods able to correct the modal response in such a way to obtain the required accuracy. Many methods have been proposed in the last years but they are meaningful only when the forcing function is expressed by an analytical function. Moreover in stochastic analysis they fail for white noise excitation. In the paper a method able to give a very accurate response for both deterministic and stochastic input is p…

Cubic smoothing splines background correction in on-line liquid chromatography–Fourier transform infrared spectrometry

2010

A background correction method for the on-line coupling of gradient liquid chromatography and Fourier transform infrared spectrometry (LC-FTIR) is proposed. The developed approach applies univariate background correction to each variable (i.e. each wave number) individually. Spectra measured in the region before and after each peak cluster are used as knots to model the variation of the eluent absorption intensity with time using cubic smoothing splines (CSS) functions. The new approach has been successfully tested on simulated as well as on real data sets obtained from injections of standard mixtures of polyethylene glycols with four different molecular weights in methanol:water, 2-propano…

Information transfer in QT-RR dynamics: Application to QT-correction

2018

ABSTRACTThe relation between the electrical properties of the heart and the beating rate is essential for the heart functioning. This relation is central when calculating the “corrected QT interval” — an important measure of the risk of potentially lethal arrhythmias. We use the transfer entropy method from information theory to quantitatively study the mutual dynamics of the ventricular action potential duration (the QT interval) and the length of the beat-to-beat (RR) interval. We show that for healthy individuals there is a strong asymmetry in the information transfer: the information flow from RR to QT dominates over the opposite flow (from QT to RR), i.e. QT depends on RR to a larger e…

Climate signals in δ13C of wood lignin methoxyl groups from high-elevation larch trees

2016

Abstract In this study, a barely used method to measure δ13C values from lignin methoxyl groups (δ13Cmethoxyl) of tree‐rings is applied to high alpine larch trees to test their potential as a climate proxy. Thirty-seven larch trees (Larix decidua Mill.) were sampled at a tree line site near Simplon Village in the Valais/Switzerland. Samples were used to measure tree-ring width, and from five individuals, δ13Cmethoxyl was determined at annual resolution from 1971 to 2009, and at pentadal resolution from 1747 to 2009. The physiological tree responses to increasing atmospheric CO2 concentration since 1850 and the corresponding decrease in δ13C (Suess effect) were corrected using a range of pub…

Possible learning and reading disorder nonmedication correction methods

2011

A correction method for dynamic analysis of linear systems

2004

Abstract This paper proposes an analytical method to improve the accuracy of the dynamic response of classically damped linear systems, as given by a standard truncated modal analysis. Upon computing the first m undamped modes of a n-degree-of-freedom system, two sets of equations in the Rn nodal space are built, which are uncoupled and govern the contribution to the response of the m computed modes and the remaining (n−m) unknown modes, respectively. The first set is solved in the Rm modal space by using the m available modes; the second set is solved in a reduced R(n−m) nodal space, without computing additional modes. Specifically, it is shown that the particular solution of the second se…

Leaf-Level Spectral Fluorescence Measurements : Comparing Methodologies for Broadleaves and Needles

2019

Successful measurements of chlorophyll fluorescence (ChlF) spectral properties (typically in the wavelength range of 650–850 nm) across plant species, environmental conditions, and stress levels are a first step towards establishing a quantitative link between solar-induced chlorophyll fluorescence (SIF), which can only be measured at discrete ChlF spectral bands, and photosynthetic functionality. Despite its importance and significance, the various methodologies for the estimation of leaf-level ChlF spectral properties have not yet been compared, especially when applied to leaves with complex morphology, such as needles. Here we present, to the best of our knowledge, a first comparison of …